Hey Paul,
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Do we really know if the acidity is important in the leaf mold
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Yes and no...

I've done quite a bit of testing but am not ready to publish details yet.
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or is it the amount of organic matter and its effect on redox potentials and, therefore, availability of iron and manganese?
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Contrary to common assumption, the highly specialized crypts from the raised peat swamp forests don't experience high levels of available micronutrients - their only supply is mere rain water!
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I propose that someone who has some of the blackwater crypts try one plant in the leaf mold and the other in leaf mold with added ground limestone or ground up eggshells added. The limestone or egg shells would keep the pH much higher. It would be interesting to see if this actually harms the growth.
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We know from earlier attempts to grow blackwater crypts that many/most can tolerate higher pH than they ever experience in nature (e.g. about pH 6). However, even if starting out with lush growth, many crypts posed problems in longterm culture and many stocks vanished within 2-3 years despite generous repotting and other measures.
I believe that with these plants we need to view their soil as an ecosystem where tampering with a single factor may have unexpected deleterious effects rather than it being a substrate which just delivers all necessary nutrients...