Just an update. I took all the ludwigia out and any other detritus that might be contributing to the DOCs. I also removed all the Duckweed and Frogbit, vacuumed the gravel, scraped the algae off the glass and cleaned out the canister filter. Spotless.
Then I siphoned off about a gallon of water every day, removing about 90% of the scum. Within 12 hours it was back again, and all the water changing caused a diatom bloom. With no floating plants, I got an algae bloom, too. On the up side, the film has a pearlescent sheen that's really quite attractive.
So, I put the Duckweed back and adjusted the spray bar to stir it into the scum, and hopefully keep it broken up. That worked for a couple days. Now the Duckweed is segregated and compacted into rotating patches and is clearly starting to die off like the Frogbit. I've even tried transplanting the biofilm to my other NPTs to see what would happen but it just doesn't take. Thankfully, the fish show absolutely no signs of stress.
I'm thinking it's time to throw in the towel on this aquarium and convert it to a NPT.
