This is an old one. lol
I haven't read your papers as I don't have time for that nor need to. All I will say that Ph Controller vs drop checker. Which is more accurate? Neither are more accurate than each other but the drop checker is more likely to be accurate r.e. CO2 because ituses a controlled solution (4dKH) whereas the Ph probe is in the tank water.
To try and assimilate CO2 to a certain Ph drop in the tank is useless. This drop can be from many variables of which CO2 is only one. There are many acids at work. Secondly the KH of your tank water changing can affect how much the drop will be.
Therefore as we know the solution in the drop checker is a certain KH then we know what the drop will be. In the tank water if there is a slight change in KH then the process is flawed immediatley.
To suggest that a setup with a Ph controller will have equal CO2 all the way round the tank whereas a tank with a drop checker and permanent injection will not is ridiculous. They will be the same.
The Ph controller will turn on/off relevant to the PH drop in the probe's area. Just as a drop checker will only give you the reading of the DCs area. You could add more probes around the tank and let the average control the CO2 but by the same argument you can use several drop checkers to see your levels.
The CO2 concentration in the water is dependent on the efficiency of the diffusion method and the circulation around the tank wether using a Ph controller or not.
The problem with using a Ph controller is that we want stable CO2 but this does not mean exactly the same all around a tank. This would be impossible without having a Tornado style circulation which would not let you have any plants or fish. We are aiming at an average and like Tom says in his article the further from the diffusor you are the lower the ppm is. Nearer to the diffusor is at toxic levels but the fish will not stay in this area. They will go in and out if they feel uncomfortable with it.
A Ph controller will turn on and off with the assumption that a certain drop is the relevant level of CO2 and therefore the further areas may fluctuate to the point that the plants in this area are constantly having to adapt to different levels and therefore not growing properly. non limiting the CO2 so that there is enough plus a bit more in the further areas means that they will grow really well.
I would say that the Ph controller used in conjunction with CO2 is nothing more than a glorified (and expensive) version of the Ph /KH chart which we all know (or at least should by now) is flawed!!!
Use it to monitor Ph levels, Use it as a safety mechanism so that it will cut off CO2 in the event od something else causing a Ph crash (but set it lower than your assumed Ph drop for CO2) but don't use it to control CO2 on or off!!!
I don't see this equipment being used in many of the succesful scapes around. I only see it being promoted by the same companies that promote substrate heating cables, and fertilisers with no N or P in them (using the no N or P as a selling tool.)
My suggestion would be save your S110. Get a coule of cheap thermometers for $2 each so you can check them against each other and get 3 or 4 cheap drop checkers $5 each. Now you've saved money there and can now afford the extra CO2. It will also save you the frustration of trying to work out why algae is growing your tank
It's not rocket science. The Ph in the tank is not solely controlled by CO2 injection and therefore the tank water cannot be used to take a Ph drop reading for use with CO2. Therefore the Ph controller although being a clever piece of kit renders itself worthless in conjunction with controlling CO2!!!!
Do I have drop checkers? Yes but more for visual signs than anything else. When I setup the CO2 level I push it until I can see the fish going to the surface and then back it off a little. Then I leave it until the bottle has run out. The DCs (and me watching the plants/fish) will tell me if anything untoward is happening!!
AC