I guess there is a typo, which has lead to mistake...
Gypsum is not (CaSO4)2 x H2O, but CaSO4 x 2H2O.
Ca=23.28% (
General Gypsum Information).
Enter 100L, 1 tsp of CaSO4x2H2O (3.1g), and you will get 8.56ppm instead of 7.6128ppm, it's x1.2 difference

Take a look please...