I have two Walstad shrimp bowls by the window and pH goes up from 7.4 to 8.8 in the afternoon when sunlight shines through. I have no fish, just shrimp and snails and I feed sparingly. KH is around 4, and gH around 8. Elevated pH is caused by photosynthetic removal of carbonic acid aka CO2, but I heard that super oxidation of minerals can also raise pH as I can observe oxygen streaming vigorously in afternoon sun.