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Use a food safe spray paint. I've done this a couple of times with a few different objects and tanks. I never had any problems as long as you let it dry thoroughly.
 

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Krylon Fusion spray paint for plastic works in an aquarium.
I have painted PVC with it, and it is fine.
For the smooth tubing I would rough it up a bit with some sand paper. It will not take much.
I just barely took the gloss off the PVC pipe and the paint stuck to it with no problems. I put on 2 coats.
 
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