I've never required air pumps for O2 levels and feel surface agitation is enough for most setups. The reason why some use pumps during the night is to avoid CO2 levels from becoming too high and possibly becoming dangerous. Although PH in nature will vary from rainfalls and changes in seasons, we are comparing it to a daily change from day to night, this may not be as "healthy" as nature's way of doing things. If your PH changes more than 0.4 between day and night, you could do a little better. If your fish don't seem bothered by your current setup, then don't change anything, they are probably used to it by now.
Due to the high CO2 levels I keep and low surface agitation, I have my CO2 powered diffuser connected to the light timer, this has proven to be the most stable in this tank, if it had more surface agitation I'd probably leave it on 24/7 but wouldn't be able to bring CO2 levels as high as I do now during the day.
It's all about balancing CO2 loss and diffusion rate, plant uptake plays a small part for tanks with moderate surface agitation/gas exchange levels.
Hope that helps
Giancarlo Podio