i don't think you'll have any issue with it, and i think some have used those types of rocks nicely is some scapes.
Yes, i am using Lava rock from Eheim for beneficial bacterias in my filter.Lava rock is probably one of the best rocks to grow moss on, and I have heard some people use very small, crushed pieces in their substrate to increase surface area for beneficial bacteria to live. And, lava rock can certainly accentuate an aquascape if used correctly. (not saying there is any correct way of course)