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Scuba tanks are even rated for higher psi so safety should be no problem if you get the fittings right. Have some friends who have done this here in the Philippines with no problem. You just need an adapter to be able to put in a regular CO2 valve.

As for taking it diving, its impossible as long as you got the fittings on already. To be sure, paint it gray and label in Carbon Dioxide.

Even CO2 fire extinguishers can be converted for used in planted tanks.
 
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