I'd be a little leery here, When you get to 10,000K bulbs they are not as incredibly different than 6,500K. Years ago when experimenting with lights on planted tanks I found an ideal combination was using GE Chroma 5,000K's with the GE 6,500K Daylight bulbs being considerably better than straight 6,500K. This is why I'm looking at building a LED fixture with a 2-1 split between 7,500K and 4,000K LED's. There is just a little more red in the 5,000K spectrum compared to the 6,500K's. So going with a 10,000K which should have less red I did very fickle about for plant growth.
However if your more concerned about a nice color appearance then I'd say you would possible be happy. But remember everyone's color taste varies some. I have heard complaints that 6,500K make the tank look to yellow, I also heard they make the tank to blue to some people?
However going back years ago I saw spectrum charts and commutations on different bulbs from different manufacturers. The true color temp seldom was a match to the advertised K temp. However the CRI values were fairly close to what was advertised. Generally the higher the K value was advertised the less accurate it was.
If you want to go that route I'd simply change out one bulb at a time and see how the plants react to it. It should not be a drastic change that way and you can get a better idea what is happening with the changes.
Note a 5,000K bulb with a CRI over 90 will be much whiter than a 10,000K bulb with a CRI in the 70's.